For stats Fenny wants +10.0% ATK and +10.6% Crit Damage.
For the Special talent, Fenny wants +8.5% Electrical Damage
Coronet has both a low base crit damage stat (30%) and a high crit chance (25% from her shotgun, 28% from her Deiwos, and 12% from her Alignment Index = 65%)
(Remember that shots against enemy weakspots have a 100% crit chance, meaning any extra crit rate mods she has are literally worthless when shooting a weakspot.)
This means that Crit DMG Amplifier mods work out to be her strongest damage increase, although when not shooting at a weakspot Crit Rate and Alignment Index mods do work out only slightly worse:
119.5% Damage factoring in crits, but with no extra Alignment Index, Crit Rate, or Crit DMG Amplifier mods
123.32% Damage with 3 max-roll Alignment Index mods
124.27% Damage with 3 max-roll Crit Rate mods
125.7% Damage with 3 max-roll Crit DMG Amplifier mods
Again though; Alignment and Crit Rate mods are useless if shooting at a weakspot, but Crit DMG Amplifier mods are her best non-ATK stat regardless of what she's shooting at.
This means that whilst a Crit DMG Amplifier mod is Coronet's best stat after ATK, Crit Rate and Alignment Index are both very good cope stats that perform very similarly when not shooting at a weakspot.
Note that if using Yao - Nightglow to support Coronet, then Crit DMG Amplifier mods are ever stronger still, due to Yao's strong crit dmg buffs and Coronets extremely high crit rate.
Being one of the OG 5* operatives, Coronet doesn't have her own designated logistics squad, so she has a few options, with two optimal squads depending on how she is played:
Amano-Iwato
Increases ADS Ballistic DMG by 10% after a crit. Max 5 Stacks. A great choice if you are ADS'ing with Coronet due to her very high crit chance.
If you only hipfire and if you don't ADS then it's obviously terrible, but Coronet's high crit rate gives Amano-Iwato great synergy with her, so ADS'ing with Amano-Iwato is the best way of using Coronet.
Mingyi
When dealing Electrical DMG, increases ATK of the equipping operative by 1% for 3 sec. Max 45 stacks. Repeated triggers will reset the duration.
Mingyi is still less total damage increase than Amano-Iwato, but Mingyi doesn't need ADS, although does require Coronet fire basically continuously.
Given that Coronet's ultimate skill is terrible and her Standard Skill doesn't need to be used often (literally once per fight with her first Manifestation), shooting continuously is basically the only thing that Coronet does in combat, so sustaining Mingyi is actually quite easy in practice.
Coronet's 5* weapon (Sunny Payback) has a 2.62s Reload SPD, so you'll need to shoot immediately after reloading, but provided you do that sustaining Mingyi is easy.
TL:DR: Use Amano-Iwato if you ADS, and Mingyi if not.