Acacia
C [Redacted] Pistol Chaos Support - Slow Slows enemies
S Chrono Echo Flying DaggerKinetic Main DPS Single-target dps with some AoE damage, albeit complex and with a steep learning curve
A Kaguya Pistol Frost Support - Debuff Debuffs enemy resistances
Bubu
S Specular Soul Dual SMG Chaos Main DPS - Hybrid Strong mostly-ballistic damage with pretty low mobility
S The Geomancer Pistol Thermal Main DPS - Ballistic High ballistic-only DPS with low mobility that requires you to manually aim every shot
Chenxing
B The Observer AR Electric Support - Skill Decent Hybrid DPS. A competent support that buffs skill damage and gives a little healing.
A Ethereal Cloud AR Electric Main DPS - Hybrid Hybrid DPS that can hit multiple enemies (or multiple parts)
SS Jade Arc Bow Electric Main DPS - Hybrid Extremely high mostly-skill dps whose skills also benefit from ballistic buffs and can crit.
Clarina
S Crimson Moon SMG Kinetic Main DPS - Skill Strong skill damage with high [forced] mobility and excellent self-healing
Cherno
C Those Two SMG Chaos Support - Slow Slows enemies, with decent damage from her ult.
A Enigma SMG Chaos Main DPS - Skill High skill damage + a little ballistic damage and DoT. Extremely terrible against mobile enemies.
Eatchel
SS The Cub Shotgun Kinetic Support - Healer Passively heals your current operative (and with some investment can also buff ATK as well)
Enya
D Big Sis Pistol Thermal Main DPS - Skill Her skills do deal some skill damage, albeit in a finicky, slow, and inaccurate way
B Exuvia Pistol Electric Support - Skill Skill damage buffs, but ideally requires both frequent shooting and dealing skill damage
S Tempest Shotgun Kinetic Main DPS - Skill High PBAoE skill damage with great mobility, albeit with a very low average range.
Fenny
B Coronet Shotgun Electric Main DPS - Ballistic Ballistic damage. Also good at Parts Breaking. Can also work as a C/B-tier support to buff RoF.
B Lionheart Shotgun Kinetic Main DPS - Ballistic Ballistic damage with good mobility.
S Pureheart SMG Thermal Main DPS - Skill Aerial sort-of-hybrid DPS that can go full AoE if needed (at the cost of DPS)
S Starshine AR Kinetic Support - Ballistic Ballistic damage buffs. Gives you full mags (=no reloading). Incompatible with some dps-ers.
Fritia
B Little Sunshine AR Thermal Support - Ballistic Adds Thermal Damage to main operatives ballistic shots
B Hush AR Thermal Main DPS - Skill Good Ultimate Skill damage, but most of combat is waiting to get enough energy for her ult.
C or S Turbo Sniper Chaos Main DPS - Ballistic High ballistic damage, extreme mobility, auto-aim, but needs her 5* weapon to sustain her dps
Haru
D The Ace Pistol Kinetic Main DPS - Hybrid Ballistic + skill damage. Long-range but low-dps.
C Absconditus Pistol Kinetic Main DPS - Skill Close-range Skill DPS
C Raikou AR Chaos Main DPS - Skill Clunky close-range high-mobility low-dps that performs poorly against mobile enemies.
Katya
A Blue Bolt Crossbow Frost Main DPS - Ballistic Ballistic damage with low mobility and high RoF
S Dawnwing AR Frost Main DPS - Skill High skill damage (and some decent ballistic damage), with high mobility
SS Rhapsody Minigun Frost Main DPS - Ballistic High ballistic damage with extreme RoF and low mobility. Always support with Tess - Phantasia.
Lyfe
B Wednesday SMG Electric Main-DPS - Ballistic Moderate ballistic damage with high RoF. Summons drones that do a little damage.
B Wild Hunt SMG Frost Main DPS - Hybrid Hybrid ballistic and skill damage
A Infinite Sight Dual SMG Kinetic Main DPS - Ballistic High ballistic damage with high mobility
Marian
S Aquila SMG Kinetic Support - Generic Aquila provides strong but generic "+damage" buffs whilst also doing some kinetic damage too.
B Queen of Pain Sniper Chaos Support - Chaos dmg Marian can debuff enemy chaos res, and if built properly can be a strong chaos support for a 4*.
E Swift Sniper Kinetic Main DPS - Ballistic Clunky sorta-Hipfire (/skill) ballistic damage.
S Riptide Shotgun Chaos Skill sub-DPS Strong skill sub-DPS with team-wide skill-damage buffing
Mauxir
B Meow SMG Frost Support - Ballistic Her ult adds a lot of Frost damage to each of the deployed operatives ballistic shots.
S Lotus Sniper Frost Main DPS - Aux Unit Summons units to autonomously and passively deal damage for her.
B Shadow Ka SMG Chaos Support - Utility Summons a target that, when damaged, causes the associated enemy to take extra damage
Mia
S Starchaser Shotgun Electric Main DPS - Ballistic Strong long-range ballistic dps. Her skill can deal skill damage over a vast area. Terrible mobility
Nerida
S Styx Envoy AR Chaos Main DPS - Skill High-mobility long-range multi-target Skill damage (Note: Only use Nerida with Marian - Riptide)
Nita
C Hands Shotgun Kinetic Main DPS Close-range/melee ballistic+skill damage
A Pulse Shotgun Thermal Main DPS - Skill Melee DPS with self-injury+healing, and limited mobility. Rating sorta depends on enemy mobility
Siris
D The Goldfish Shotgun Kinetic Main DPS Ballistic DPS with strong self-survivability buffs
S Freefin Pistol Thermal Support - Skill Strong skill-damage support with potentially unlimited duration buff
A Ksana Shotgun Thermal Main DPS - Skill Bulky skill DPS with very high [forced] mobility.
Tess
SS The Magician Sniper Electric Support - U-Energy Ultimate-Energy battery.
S Phantasia AR Frost Support - Ballistic Adds strong Frost Damage to each of the deployed operatives ballistic shots.
Vidya
SS Agave Pistol Electric Parts Break Her skill is incredible at breaking destructible parts, with auto-aim and some AoE too.
SS Celestial Swan Sniper Chaos Support - Debuffer Debuffs enemy Defence and Damage Resistance. The strongest support in the game by-far.
Yao
A Quiet Quitter Sniper Frost Support - Healer Deploys a drone that provides PBAoE healing
B Winter Solstice Sniper Thermal Main DPS - Ballistic Relatively "standard" bolt-action ADS ballistic sniper that requires you to precisely aim.
S Nightglow SMG Electric Support - Ballistic Buffs allies ballistic DMG & ATK, and reduces enemy Crit Resistance